1-Butanol → HCID 13255805, compound

HRID 2295912Notes

Reaction equation

HRID 2295912 reaction equation
[OH-:1].[K+].Cl[C:4](Cl)(Cl)[CH2:5][C:6]1[C:11]([Cl:12])=[CH:10][C:9]([Cl:13])=[CH:8][C:7]=1[Cl:14].[CH2:17]([OH:21])[CH2:18][CH2:19][CH3:20]>>[Cl:14][C:7]1[CH:8]=[C:9]([Cl:13])[CH:10]=[C:11]([Cl:12])[C:6]=1[CH2:5][C:4]([O:21][CH2:17][CH2:18][CH2:19][CH3:20])=[O:1]

Participants

4

Reactant 3

HCID 2631-ButanolHCID 14797Potassium HydroxideHCID 204743061,3,5-Trichloro-2-(2,2,2-trichloroethyl)benzene

Product 1

HCID 13255805HCID 13255805, compound

Procedure

A 9.0 g. portion of potassium hydroxide of the grade described in the examples above was combined with 50 ml. of butanol, and the mixture was stirred for 15 minutes. To it was added 5 g. of 1,1,1-trichloro-2-(2,4,6-trichlorophenyl)ethane, and the mixture was stirred under reflux at 115° for 7 hours. It was then cooled to ambient temperature overnight, and worked up substantially as described in Example 4 above to obtain 3.9 g. of product, 96% pure by vapor phase chromatography. The product was distilled at 155°-162° under 0.35 torr to obtain 3.4 g. of purified product.

Workup

  1. additionTo it was added 5 g
  2. temperatureunder reflux at 115° for 7 hours
  3. customto obtain 3.9 g
  4. distillationThe product was distilled at 155°-162° under 0.35 torr
  5. customto obtain 3.4 g

Sources & evidence

ORD record
ord-0775402b18354844b3e3e4c86865cdef
Source dataset
uspto-grants-1984_01
Patent number
US04426536

Reaction notes

Loading…