(2,4-Dichlorophenoxy)acetyl chloride → HCID 53700116, compound

HRID 2296411Notes

Reaction equation

HRID 2296411 reaction equation
ClC1C=C(Cl)C=CC=1[O:4]CC(Cl)=O.[Cl:14][C:15]1[CH:52]=[C:51]([C:53]([F:56])([F:55])[F:54])[CH:50]=[CH:49][C:16]=1[O:17][C:18]1[CH:19]=[CH:20][C:21]([N+:46]([O-:48])=[O:47])=[C:22]([CH:45]=1)[C:23]([O:25][CH2:26][CH2:27]OC(=O)CCOC1C=CC([N+]([O-])=O)=CC=1C#N)=[O:24].[Cl:57][C:58]1[CH:68]=[C:67]([Cl:69])[CH:66]=[C:65]([Cl:70])[C:59]=1[O:60][CH2:61][C:62](Cl)=[O:63]>>[Cl:14][C:15]1[CH:52]=[C:51]([C:53]([F:54])([F:56])[F:55])[CH:50]=[CH:49][C:16]=1[O:17][C:18]1[CH:19]=[CH:20][C:21]([N+:46]([O-:48])=[O:47])=[C:22]([CH:45]=1)[C:23]([O:25][CH2:26][CH2:27][O:63][C:62](=[O:4])[CH2:61][O:60][C:59]1[C:58]([Cl:57])=[CH:68][C:67]([Cl:69])=[CH:66][C:65]=1[Cl:70])=[O:24]

Participants

4

Reactant 3

HCID 69887(2,4-Dichlorophenoxy)acetyl chlorideHCID 3027202,4,6-trichlorophenoxyacetyl chlorideHCID 54232885HCID 54232885, compound

Product 1

HCID 53700116HCID 53700116, compound

Procedure

Other compounds of this type are also prepared according to this example by proper substitution of the 2,4-dichlorophenoxyacetyl chloride reactant. For instance, 2-[(2-cyano-4-nitrophenoxy)-propionyloxy]ethyl 5-(2-chloro-4-trifluoromethylphenoxy)-2-nitrobenzoate is prepared by substituting 2-[(2-cyano-4-nitrophenoxy)propionyl]chloride; 2-(2,4,6-trichlorophenoxyacetoxy)ethyl 5-(2-chloro-4-trifluoromethylphenoxy)-2-nitrobenzoate is prepared by substituting 2-(2,4,6-trichlorophenoxyacetyl chloride; etc.

Workup

  1. customOther compounds of this type are also prepared

Sources & evidence

ORD record
ord-b0ea414b819843e28f38cca0d4bacf88
Source dataset
uspto-grants-1984_01
Patent number
US04429146

Reaction notes

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