HCID 13651185, compound → 3-tert-Butylaniline

HRID 2296504Notes

Reaction equation

HRID 2296504 reaction equation
[C:1]([CH:5]1[CH2:10][CH2:9][CH2:8][CH:7]([NH2:11])[CH2:6]1)([CH3:4])([CH3:3])[CH3:2]>[Pd]>[C:1]([C:5]1[CH:6]=[C:7]([CH:8]=[CH:9][CH:10]=1)[NH2:11])([CH3:4])([CH3:2])[CH3:3]

Participants

3

Reactant 1

HCID 13651185HCID 13651185, compound

Product 1

HCID 793343-tert-ButylanilineYield 95%

Reagents, catalysts & solvents 1

HCID 23938PalladiumCatalyst

Procedure

The procedure described in Example 27 is followed, using a catalyst which contains 1.0% by weight of palladium on a lithium/aluminum spinel. Starting from 3-tert-butylcyclohexylamine, there is obtained m-tert-butylaniline (boiling point=72°-73° C./0.27 mbar) in a yield of 95% of the theory.

Sources & evidence

ORD record
ord-f58977fe75914aa99b437b743687a933
Source dataset
uspto-grants-1984_01
Patent number
US04429155

Reaction notes

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