HCID 11404912, compound → HCID 13628732, compound

HRID 2296927Notes

Reaction equation

HRID 2296927 reaction equation
[N:1]1[N:2]([C:10]2[CH:15]=[C:14]([CH3:16])[CH:13]=[C:12]([CH:17]([CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[CH:18]=[CH2:19])[C:11]=2[OH:25])[N:3]=[C:4]2[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=12>[Pd].CC([O-])=O.CC([O-])=O.[Pb+2].CCCCCC>[N:1]1[N:2]([C:10]2[CH:15]=[C:14]([CH3:16])[CH:13]=[C:12]([CH:17]([CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[CH2:18][CH3:19])[C:11]=2[OH:25])[N:3]=[C:4]2[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=12

Participants

4

Reactant 1

HCID 11404912HCID 11404912, compound

Product 1

HCID 13628732HCID 13628732, compound

Reagents, catalysts & solvents 2

HCID 131709914Lindlars catalystCatalystHCID 8058HexaneSolvent

Procedure

0.5 g of 2-(benzotriazole-2-yl)-4-methyl-6-(1-octen-3-yl)-phenol and a trace of “Lindlar catalyst” (Fluka) in 20 ml of hexane was hydrogenated for 4 hours under normal hydrogen pressure. Then the reaction mixture was filtered and concentrated to yield (quantitatively) 2-(benzotriazole-2-yl)-4-methyl-6-(3-octyl)-phenol as a yellow liquid.

Workup

  1. filtrationThen the reaction mixture was filtered
  2. concentrationconcentrated

Sources & evidence

ORD record
ord-5f93507192b2413cb0ca2d7976d7cd8f
Source dataset
uspto-grants-2002_12
Patent number
US06489486B2

Reaction notes

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