HRID2297361

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID11448

tert-Butyl methacrylate

C8H14O2

结构：C=C(C)C(=O)OCCC[Si](O[Si](C)(C)C)(O[Si](C)(C)C)O[Si](C)(C)C

HCID123371

3-(3,3,3-Trimethyl-1,1-bis((trimethylsilyl)oxy)disiloxanyl)propyl methacrylate

C16H38O5Si4

HCID18381205

未命名化合物

PRODUCTS

生成物

结构：C=C(C)C(=O)OC(C)(C)C.C=C(C)C(=O)OC1C2CC3C(=O)OC1C3C2.C=C(C)C(=O)OCCC[Si](O[Si](C)(C)C)(O[Si](C)(C)C)O[Si](C)(C)C

HCID70157708

未命名化合物

PROCEDURE

实验过程

A copolymer was synthesized as in Polymer Synthesis Example 1 except that 3-[tris(trimethylsilyloxy)silyl]propyl methacrylate and t-butyl methacrylate were used instead of 1,4,4-trimethyl-4-silacyclohexyl methacrylate. The polymer was confirmed by the light scattering method to have a weight average molecular weight of 13,000 g/mol and by the GPC elution curve to have a dispersity (Mw/Mn) of 1.78. By 1H-NMR analysis, the copolymer was found to contain the components in a ratio of approximately 2:5:3.

WORKUP

后处理

washby the GPC elution curve

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-f11f81e9aa554f2595304d658ef37647
来源数据集: uspto-grants-2002_12
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06492089B2
来源说明: uspto-grants-2002_12

反应 SMILES

[C:1]([O:6][CH2:7][CH2:8][CH2:9][Si:10]([O:21][Si:22]([CH3:25])([CH3:24])[CH3:23])([O:16][Si:17]([CH3:20])([CH3:19])[CH3:18])[O:11][Si:12]([CH3:15])([CH3:14])[CH3:13])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:26]([O:31][C:32]([CH3:35])([CH3:34])[CH3:33])(=[O:30])[C:27]([CH3:29])=[CH2:28].[C:36]([O:41][C:42]1(C)[CH2:47][CH2:46][Si](C)(C)CC1)(=[O:40])[C:37](C)=C>>[C:1]([O:6][CH2:7][CH2:8][CH2:9][Si:10]([O:11][Si:12]([CH3:15])([CH3:13])[CH3:14])([O:21][Si:22]([CH3:25])([CH3:24])[CH3:23])[O:16][Si:17]([CH3:20])([CH3:19])[CH3:18])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:26]([O:31][C:32]([CH3:35])([CH3:34])[CH3:33])(=[O:30])[C:27]([CH3:29])=[CH2:28].[C:1]([O:6][CH:7]1[CH:42]2[CH:47]3[CH:37]([CH2:9][CH:8]1[CH2:46]3)[C:36](=[O:40])[O:41]2)(=[O:5])[C:2]([CH3:4])=[CH2:3]