HRID229779

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID143191

7-(Diethylamino)-2-oxo-2H-1-benzopyran-3-carbaldehyde

C14H15NO3

结构：C[N+](C)(C)CC(=O)O.Cc1cc[n+](CCCCCC(=O)O)c2ccc(S(=O)(=O)[O-])cc12

HCID131727539

未命名化合物

PRODUCTS

生成物

结构：CCN(CC)c1ccc2cc(/C=C/c3cc[n+](CCCCCC(=O)O)c4ccc(S(=O)(=O)O)cc34)c(=O)oc2c1.C[N+](C)(C)CC(=O)O

HCID131727538

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID22242641

Methanol--water (1/1)

CH6O2

PROCEDURE

实验过程

0.2 mmol 7-diethylamino-2-oxo-2H-chromene-3-carbaldehyde and 0.2 mmol 1-(5-carboxy-pentyl)-4-methyl-6-sulfonato-chinolinium betaine are converted according to the general directions given above. Column chromatography: SiO2 (RP 18), eluent: methanol/water.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-ef5b89c3f6384f20afb9e0e083ac7176
来源数据集: uspto-grants-2009_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US07563907B2
来源说明: uspto-grants-2009_07

反应 SMILES

[CH2:1]([N:3]([CH2:17][CH3:18])[C:4]1[CH:13]=[C:12]2[C:7]([CH:8]=[C:9]([CH:15]=O)[C:10](=[O:14])[O:11]2)=[CH:6][CH:5]=1)[CH3:2].[C:19]([CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][N+:27]1[C:36]2[C:31](=[CH:32][C:33]([S:37]([O-:40])(=[O:39])=[O:38])=[CH:34][CH:35]=2)[C:30]([CH3:41])=[CH:29][CH:28]=1)([OH:21])=[O:20].[CH3:42][N+:43]([CH2:46][C:47]([OH:49])=[O:48])([CH3:45])[CH3:44]>CO.O>[C:19]([CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][N+:27]1[C:36]2[C:31](=[CH:32][C:33]([S:37]([OH:40])(=[O:39])=[O:38])=[CH:34][CH:35]=2)[C:30](/[CH:41]=[CH:15]/[C:9]2[C:10](=[O:14])[O:11][C:12]3[C:7]([CH:8]=2)=[CH:6][CH:5]=[C:4]([N:3]([CH2:17][CH3:18])[CH2:1][CH3:2])[CH:13]=3)=[CH:29][CH:28]=1)([OH:21])=[O:20].[CH3:42][N+:43]([CH2:46][C:47]([OH:49])=[O:48])([CH3:45])[CH3:44]