HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium triacetoxyborohydride → HCID 22166476, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium triacetoxyborohydride | HCID 5049666 | — |
| Reactant | HCID 18338590 | HCID 18338590 | — |
| Reactant | HCID 22166479 | HCID 22166479 | — |
| Product | HCID 22166476 | HCID 22166476 | 28% |
Reaction Steps
Crude methyl 4-tert-butoxycarbonyl-2-oxobutanoate (1.65 g, 7.6 mmol) and sodium triacetoxyborohydride (1.6 g, 7.6 mmol) were reacted by the same procedure as described in Example 1 for the preparation of methyl 7-tert-butoxycarbonyl-2-hydroxyheptanoate to give the title compound (460 mg, 28% 2 steps) as a colorless liquid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06492550B2 |
| Source dataset | uspto-grants-2002_12 |
| ORD ID | ord-8bfaccc60487445692eef4d34d3f5887 |
| Source note | uspto-grants-2002_12 |