3,7-Dimethyl-6octenyl-2-oxopropanoate → 3,7-Dimethyl-6-octenyl 3-methyl-2-oxopentanoate

HRID 2298513Notes

Reaction equation

HRID 2298513 reaction equation
[CH3:1][CH:2]([CH2:11][CH2:12][CH:13]=[C:14]([CH3:16])[CH3:15])[CH2:3][CH2:4]CC(=O)C([O-])=O.CC(CCC=C(C)C)[CH2:19][CH2:20][CH:21]([CH3:27])[C:22](=[O:26])[C:23]([O-:25])=[O:24]>>[CH3:27][CH:21]([CH2:20][CH3:19])[C:22](=[O:26])[C:23]([O:25][CH2:4][CH2:3][CH:2]([CH3:1])[CH2:11][CH2:12][CH:13]=[C:14]([CH3:15])[CH3:16])=[O:24]

Participants

3

Reactant 2

HCID 865836323,7-Dimethyl-6octenyl-2-oxopropanoate3×HCID 865836333,7-Dimethyl-6octenyl-2-oxobutanoate2×

Product 1

HCID 129651843,7-Dimethyl-6-octenyl 3-methyl-2-oxopentanoate

Procedure

MS (EI): 268 (M+, 1); 250 (1); 240 (1); 207 (1); 183 (2); 155 (2); 138 (10); 123 (14); 109 (7); 95 (18); 85 (32); 81 (26); 69 (51); 57 (100); 41 (53); 29 (18).

Sources & evidence

ORD record
ord-121fd6485bee415eac69e2f0863bc025
Source dataset
uspto-grants-2002_12
Patent number
US06492323B2

Reaction notes

Loading…