3,7-Dimethyl-6-octenyl 2-oxopentanoate → 3,7-Dimethyl-6-octenyl (cyclohexyl)oxoacetate

HRID 2298515Notes

Reaction equation

HRID 2298515 reaction equation
C[CH:2]([CH2:11][CH2:12]C=C(C)C)[CH2:3][CH2:4][CH2:5][C:6](=[O:10])[C:7]([O-:9])=[O:8].O=C(CCC)C(O[CH2:22][CH2:23][CH:24]([CH3:31])[CH2:25][CH2:26][CH:27]=[C:28]([CH3:30])[CH3:29])=O.CC(CCC=C(C)C)CCC(C)C(=O)C([O-])=O.CC(CC)C(=O)C(OCCC(C)CCC=C(C)C)=O.C(C1C=CC(C(=O)C(OCCC(C)CCC=C(C)C)=O)=CC=1)(=O)C.CC(CCCCCCCCCCCC)C(=O)C(OCCC(C)CCC=C(C)C)=O.O=C(C1C=CC=CC=1)C(OCCC(C)CCC=C(C)C)=O.O=C(CCCCCCCCCCCCCC)C(OCCC(C)CCC=C(C)C)=O>>[CH:5]1([C:6](=[O:10])[C:7]([O:9][CH2:22][CH2:23][CH:24]([CH3:31])[CH2:25][CH2:26][CH:27]=[C:28]([CH3:30])[CH3:29])=[O:8])[CH2:4][CH2:3][CH2:2][CH2:11][CH2:12]1

Participants

9

Reactant 8

HCID 129651833,7-Dimethyl-6-octenyl 2-oxopentanoate8×HCID 129651843,7-Dimethyl-6-octenyl 3-methyl-2-oxopentanoate3×HCID 129651863,7-Dimethyl-6-octenyl 2-oxohexadecanoateHCID 129651873,7-Dimethyl-6-octenyl 3-methyl-2-oxopentadecanoateHCID 129781333,7-Dimethyl-6-octenyl oxo(phenyl)acetateHCID 129781343,7-Dimethyl-6-octenyl (4-acetylphenyl)oxoacetate2×HCID 865836323,7-Dimethyl-6octenyl-2-oxopropanoate5×HCID 865836333,7-Dimethyl-6octenyl-2-oxobutanoate5×

Product 1

HCID 129651883,7-Dimethyl-6-octenyl (cyclohexyl)oxoacetate

Procedure

MS (EI): 294 (M+, 1); 276 (1); 266 (1); 233 (1); 193 (1); 183 (4); 165 (1); 155 (2); 139 (2); 138 (13); 137 (4); 123 (14); 112 (2); 111 (16); 110 (3); 109 (6); 96 (4); 95 (16); 94 (2); 84 (7); 83 (100); 82 (15); 81 (22); 80 (3); 70 (2); 69 (29); 68 (4); 67 (11); 56 (4); 55 (42); 54 (3); 53 (5); 43 (4); 42 (4); 41 (38); 39 (8); 29 (6); 27 (4),

Sources & evidence

ORD record
ord-a31b1ecaf48f4f54be07958a230b3909
Source dataset
uspto-grants-2002_12
Patent number
US06492323B2

Reaction notes

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