3,7-Dimethyl-6-octenyl 3-methyl-2-oxopentanoate → (E)-3,7-Dimethyl-2,6-octadienyl (cyclohexyl)oxoacetate

HRID 2298516Notes

Reaction equation

HRID 2298516 reaction equation
CC(CC)C(=O)C(OCCC(C)CCC=C(C)C)=O.C([C:23]1[CH:28]=[CH:27][C:26]([C:29](=[O:43])[C:30]([O:32][CH2:33][CH2:34][CH:35]([CH3:42])[CH2:36][CH2:37][CH:38]=[C:39]([CH3:41])[CH3:40])=[O:31])=[CH:25][CH:24]=1)(=O)C.CC(CCC=C(C)C)CCC(C)C(=O)C([O-])=O.CC(CCC=C(C)C)CCCC(=O)C([O-])=O.O=C(C1C=CC=CC=1)C(OCCC(C)CCC=C(C)C)=O>>[CH:26]1([C:29](=[O:43])[C:30]([O:32][CH2:33]/[CH:34]=[C:35](\[CH3:42])/[CH2:36][CH2:37][CH:38]=[C:39]([CH3:40])[CH3:41])=[O:31])[CH2:27][CH2:28][CH2:23][CH2:24][CH2:25]1

Participants

6

Reactant 5

HCID 129651843,7-Dimethyl-6-octenyl 3-methyl-2-oxopentanoate6×HCID 129781333,7-Dimethyl-6-octenyl oxo(phenyl)acetate3×HCID 129781343,7-Dimethyl-6-octenyl (4-acetylphenyl)oxoacetateHCID 865836323,7-Dimethyl-6octenyl-2-oxopropanoate6×HCID 865836333,7-Dimethyl-6octenyl-2-oxobutanoate3×

Product 1

HCID 12965189(E)-3,7-Dimethyl-2,6-octadienyl (cyclohexyl)oxoacetate

Procedure

MS (EI): 184 (M+, 2); 112 (3); 111 (33); 110 (3); 84 (6); 83 (100); 81 (3); 79 (2); 77 (1); 68 (1); 67 (5); 65 (1); 56 (3); 55 (54); 54 (5); 53 (5); 51 (1); 43 (2); 42 (3); 41 (23); 40 (2); 39 (12); 30 (1); 29 (20); 28 (3); 27 (13); 26 (1).

Sources & evidence

ORD record
ord-47cc33013f7e463783195370e3e87762
Source dataset
uspto-grants-2002_12
Patent number
US06492323B2

Reaction notes

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