3,7-Dimethyl-6-octenyl 2-oxopentanoate → (E)-3,7-Dimethyl-2,6-octadienyl 3-methyl-2-oxopentanoate

HRID 2298522Notes

Reaction equation

HRID 2298522 reaction equation
[CH3:1][CH:2]([CH2:11][CH2:12][CH:13]=[C:14]([CH3:16])[CH3:15])[CH2:3][CH2:4]CC(=O)C([O-])=O.[CH3:17][CH:18]([CH2:34][CH3:35])[C:19](=[O:33])[C:20]([O:22]CCC(C)CCC=C(C)C)=[O:21].C(C1C=CC(C(=O)C(OCCC(C)CCC=C(C)C)=O)=CC=1)(=O)C.O=C(C1C=CC=CC=1)C(OCCC(C)CCC=C(C)C)=O.CC(CCC=C(C)C)CCC(C)C(=O)C([O-])=O.C1(C(=O)C(OC/C=C(\C)/CCC=C(C)C)=O)CCCCC1.C1(C(=O)C(OCCC(C)CCC=C(C)C)=O)CCCCC1.O=C(CCC)C(OCCC(C)CCC=C(C)C)=O.C1(C(=O)C(OCC2C=CC(OC)=CC=2)=O)CCCCC1>>[CH3:17][CH:18]([CH2:34][CH3:35])[C:19](=[O:33])[C:20]([O:22][CH2:4]/[CH:3]=[C:2](\[CH3:1])/[CH2:11][CH2:12][CH:13]=[C:14]([CH3:15])[CH3:16])=[O:21]

Participants

10

Reactant 9

HCID 129651833,7-Dimethyl-6-octenyl 2-oxopentanoateHCID 129651843,7-Dimethyl-6-octenyl 3-methyl-2-oxopentanoate4×HCID 129651883,7-Dimethyl-6-octenyl (cyclohexyl)oxoacetateHCID 12965189(E)-3,7-Dimethyl-2,6-octadienyl (cyclohexyl)oxoacetateHCID 129781333,7-Dimethyl-6-octenyl oxo(phenyl)acetate4×HCID 129781343,7-Dimethyl-6-octenyl (4-acetylphenyl)oxoacetate4×HCID 183366714-Methoxybenzyl (cyclohexyl)oxoacetate2×HCID 865836323,7-Dimethyl-6octenyl-2-oxopropanoate15×HCID 865836333,7-Dimethyl-6octenyl-2-oxobutanoate10×

Product 1

HCID 12965185(E)-3,7-Dimethyl-2,6-octadienyl 3-methyl-2-oxopentanoate

Procedure

MS (EI): 266 (M+, 1); 181 (1); 179 (1); 153 (1); 138 (3); 137 (28); 136 (6); 135 (5); 123 (1); 122 (1); 121 (2); 109 (1); 107 82); 96 (2); 95 (10); 94 (2); 93 (6); 92 (2); 91 (3); 85 (9); 83 (1); 82 (4); 81 (52); 80 (2); 79 (3); 78 (1); 77 (3); 71 (1); 70 (6); 69 (100); 68 (12); 67 (12); 66 (1); 65 (2); 58 (2); 57 (30); 56 (1); 55 (5); 54 (1); 53 (6); 51 (1); 43 (1); 42 (2); 41 (26); 40 (2); 39 (5) 29 (5); 28 (1); 27 (2).

Sources & evidence

ORD record
ord-50a48778a03a4f4ebf158228fd5a6de2
Source dataset
uspto-grants-2002_12
Patent number
US06492323B2

Reaction notes

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