Ethanol → HCID 86596485, compound

HRID 229885Notes

Reaction equation

[CH2:1]([OH:3])C.[S:4](=[O:8])(=[O:7])([OH:6])[OH:5].[CH:9]([Cl:12])([Cl:11])[Cl:10]>>[CH:9]([Cl:12])([Cl:11])[Cl:10].[CH3:1][OH:3].[S:4](=[O:6])(=[O:5])([OH:8])[OH:7]

Participants

Reactant 3

HCID 702Ethanol

HCID 1118Sulfuric Acid

HCID 6212Chloroform

Product 1

HCID 86596485HCID 86596485, compound

Procedure

A colorless solid (0.064 g, yield: 67.4%) was obtained through a reaction conducted as in example 2 except that the reactants were replaced by compound (117) prepared in example 17 (0.1 g), ethanol (83.3 mL), chloroform (83.3 mL), and sulfuric acid (36 N, 0.3 mL). IR analysis of the resulting product revealed the existence of an absorption band that suggested an acetoxy group at 1740 cm−1. 1H-NMR analysis revealed that the product consists of a compound (138) and the compound (117) (content of compound (138): 66.3 mol %).

Sources & evidence

ORD record: ord-2b0f52a1b5044dc0bf758c3aad08fea8
Source dataset: uspto-grants-2009_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07563917B2

Reaction notes

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