HRID2301694

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID7923

2,5-Furandione

C4H2O3

HCID91537

2,2'-Azobis[2,4-dimethylvaleronitrile]

C14H24N4

HCID15607334

Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, 1,1-dimethylethyl ester

C12H18O2

HCID18345689

3-[(Bicyclo[2.2.1]hept-5-en-2-yl)(hydroxy)methyl]oxolan-2-one

C12H16O3

PRODUCTS

生成物

结构：CC(C)(C)OC(=O)C1CC2C=CC1C2.O=C1C=CC(=O)O1.O=C1OCCC1C(O)C1CC2C=CC1C2

HCID86584390

未命名化合物

PROCEDURE

实验过程

Polymerization reaction of tert-butyl 5-norbornene-2-carboxylate, Monomer 1, and maleic anhydride was effected using 2,2′-azobis(2,4-dimethylvaleronitrile) as the initiator, yielding an alternating copolymer of tert-butyl 5-norbornene-2-carboxylate/α-[hydroxy(5-norbornen-2-yl)methyl]-γ-butyrolactone/maleic anhydride (copolymerization ratio 4/1/5).

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-d61fc84b384e4c3fa7c9daff40847b54
来源数据集: uspto-grants-2002_12
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06500961B2
来源说明: uspto-grants-2002_12

反应 SMILES

[CH:1]12[CH2:7][CH:4]([CH:5]=[CH:6]1)[CH2:3][CH:2]2[C:8]([O:10][C:11]([CH3:14])([CH3:13])[CH3:12])=[O:9].[OH:15][CH:16]([CH:23]1[CH2:28][CH:27]2[CH2:29][CH:24]1[CH:25]=[CH:26]2)[CH:17]1[CH2:22][CH2:21][O:20][C:18]1=[O:19].[C:30]1(=[O:36])[O:35][C:33](=[O:34])[CH:32]=[CH:31]1.N(C(C)(CC(C)C)C#N)=NC(C)(CC(C)C)C#N>>[CH:1]12[CH2:7][CH:4]([CH:5]=[CH:6]1)[CH2:3][CH:2]2[C:8]([O:10][C:11]([CH3:14])([CH3:13])[CH3:12])=[O:9].[OH:15][CH:16]([CH:23]1[CH2:28][CH:27]2[CH2:29][CH:24]1[CH:25]=[CH:26]2)[CH:17]1[CH2:22][CH2:21][O:20][C:18]1=[O:19].[C:33]1(=[O:34])[O:35][C:30](=[O:36])[CH:31]=[CH:32]1