Aluminum(III) Chloride → HCID 86758389, compound

HRID 2301904Notes

Reaction equation

HRID 2301904 reaction equation
[OH:1][C:2]1[CH:3]=[CH:4][C:5]2[C:18]3[C:17]=1[C:16](=[O:19])[C:15]1[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=1)[C:9]=3[CH:8]=[CH:7][CH:6]=2.[Cl-].[Al+3:21].[Cl-].[Cl-]>C1(C)C=CC=CC=1>[Al+3:21].[O-:1][C:2]1[CH:3]=[CH:4][C:5]2[C:18]3[C:17]=1[C:16](=[O:19])[C:15]1[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=1)[C:9]=3[CH:8]=[CH:7][CH:6]=2.[O-:1][C:2]1[CH:3]=[CH:4][C:5]2[C:18]3[C:17]=1[C:16](=[O:19])[C:15]1[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=1)[C:9]=3[CH:8]=[CH:7][CH:6]=2.[O-:1][C:2]1[CH:3]=[CH:4][C:5]2[C:18]3[C:17]=1[C:16](=[O:19])[C:15]1[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=1)[C:9]=3[CH:8]=[CH:7][CH:6]=2

Participants

4

Reactant 2

HCID 6451240Aluminum(III) ChlorideHCID 12820459HCID 12820459, compound

Product 1

HCID 86758389HCID 86758389, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Conditions

Temperature
110 °C

Procedure

6-Hydroxy benzanthrone (1.0 g) was placed in a 100 mL round-bottom flask. Dry toluene (50 mL) was added to the flask together with aluminum chloride (0.113 g). The solution turned yellow-orange, and a precipitate began to form. The mixture was refluxed at 110° C. overnight. The flask was then cooled and the contents filtered. Crude yield 0.62 g, mp>300° C.

Workup

  1. customto form
  2. temperatureThe flask was then cooled
  3. filtrationthe contents filtered

Sources & evidence

ORD record
ord-af07b38a68a24e24b9c32043b2b7c7d7
Source dataset
uspto-grants-2002_08
Patent number
US06428912B1

Reaction notes

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