1-Dodecanethiol → 1-(Chlorosulfanyl)dodecane

HRID 2301907Notes

Reaction equation

HRID 2301907 reaction equation
[CH2:1]([SH:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].S(Cl)([Cl:17])(=O)=O>C(Cl)(Cl)Cl>[CH2:1]([S:13][Cl:17])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]

Participants

4

Reactant 2

HCID 81951-DodecanethiolHCID 24648Sulfuryl chloride

Product 1

HCID 156071481-(Chlorosulfanyl)dodecane

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

To a solution of dodecane thiol (1.00 mL, 4.17 mmol, Aldrich Chemical Company) in 20 mL CHCl3 was added sulfuryl chloride (0.74 mL, 9.18 mmol, Aldrich Chemical Company), and the resulting mixture was stirred at room temperature for 18 h. Removal of solvent (aspirator), afforded dodecansulfenyl chloride that was determined to be sufficiently pure by 1H NMR.

Workup

  1. customRemoval of solvent (aspirator)

Sources & evidence

ORD record
ord-7c62683e26604d96836ca3df37c8dc5f
Source dataset
uspto-grants-2002_08
Patent number
US06429200B1

Reaction notes

Loading…