Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|
| Edukt | Butanedione | HCID 650 | — |
| Edukt | N-Hydroxyphthalimide | HCID 10665 | — |
| Edukt | 1,3-Dimethyladamantane | HCID 12800 | — |
| Katalysator | Cobalt diacetate | HCID 6277 | — |
| Lösungsmittel | Acetic Acid | HCID 176 | — |
| Produkt | 1-Acetyl-3,5-dimethyl Adamantane | HCID 12113124 | 58% |
| Produkt | 1-Acetyl-3,5-dimethyl-7-adamantanol | HCID 13464074 | 22% |
Reaktionsschritte
A mixture of 3 mmol of 1,3-dimethyladamantane, 18 mmol of biacetyl, 0.3 mmol of N-hydroxyphthalimide, 0.015 mmol of cobalt (II) acetate, and 3 ml of acetic acid was stirred at 75° C. under an oxygen atmosphere (1 atm) for 8 hours. Products in the reaction mixture were found, by gas chromatographic analysis, to be 1-acetyl-3,5-dimethyladamantane (yield 58%), and 1-acetyl-3,5-dimethyl-7-adamantanol (yield 22%) at a conversion rate of 1,3-dimethyladamantane of 94%.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patentnummer | US06429314B1 |
|---|
| Quelldatensatz | uspto-grants-2002_08 |
|---|
| ORD ID | ord-a56293a0b6aa4cf699400b44623797c9 |
|---|
| Quellennotiz | uspto-grants-2002_08 |
|---|
