Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | Butanedione | HCID 650 | — |
| Reactant | Methyl tricyclo(3.3.1.13,7)dec-1-yl ketone | HCID 123126 | — |
| Catalyst | Cobalt diacetate | HCID 6277 | — |
| Product | 1-Acetyl-3-hydroxyadamantane | HCID 591896 | 29% |
| Product | 1,3-Diacetyladamantane | HCID 2843255 | 34% |
| Product | 1,3-Diacetyl-5-adamantanol | HCID 12113142 | 2% |
| Product | 1-Acetyl-4-adamantanone | HCID 22320000 | 5% |
Reaction Steps
A mixture of 3 mmol of 1-acetyladamantane, 18 mmol of biacetyl, 0.015 mmol of cobalt(II) acetate, and 3 ml of acetic acid was stirred at 60° C. under an oxygen atmosphere (1 atm) for 4 hours. Products in the reaction mixture were found, by gas chromatographic analysis, to be 1,3-diacetyladamantane (yield 34%), 1-acetyl-3-adamantanol (yield 29%), and 1,3-diacetyl-5-adamantanol (yield 2%), 1-acetyl-4-adamantanone (yield 5%), at a conversion rate from 1-acetyladamantane of 80%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06429314B1 |
|---|
| Source dataset | uspto-grants-2002_08 |
|---|
| ORD ID | ord-257f6af3ea0948d1ae0be5fc459546f6 |
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| Source note | uspto-grants-2002_08 |
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