Allyl bromide → HCID 18461547, compound

Participants

Reaction Steps

Analogously to the procedure of Example 1, the title compound is was prepared from 1.2 g (9.5 nmuol) of hexahydro-cyclopenta[b]furan-2-one, 10 ml of 1 molar lithium bis-(trimethylsilyl)-amide solution in THF and 1.29 g (9.5 mmol) of allyl bromide in 20 ml of THF. Yield: 1.25 g (79%) of a colourless oil. 1H-NMR(200 MHz; [d6]-DMSO): δ[ppm]: 1.47-1.89 (br m,6H), 2.15-2.55 (br m,4H), 4.41 (m,1H), 5.12 (dd,1H), 5.18 (dd,1H), 5.76 (ddt,1H)

Provenance & Evidence