HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2304953Generated: October 25, 2026
Chlorotrimethylsilane → 1-Chloro-3,7-dimethyl-octa-2,6-diene
https://huagongshe.com/reaction/2304953
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Chlorotrimethylsilane | HCID 6397 | — |
| Reactant | Linalool | HCID 6549 | — |
| Catalyst | Bismuthyl (ion) | HCID 5237718 | — |
| Product | 1-Chloro-3,7-dimethyl-octa-2,6-diene | HCID 99106 | 83.2% |
Reaction Steps
To a mixture of 170 g linalool and 20 mg bismuth(III)-oxide heated to 60° C., 130.5 g trimethylchlorosilane were added. Then, the mixture was cooled to room temperature and the organic layer was separated. The resulting oil was purified by distillation to yield 158.35 g of a colorless oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06437150B1 |
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| Source dataset | uspto-grants-2002_08 |
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| ORD ID | ord-31741ba505834e94b3832c3054c89a99 |
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| Source note | uspto-grants-2002_08 |
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