4-Nonylphenol → HCID 12496141, compound

HRID 2305009Notes

Reaction equation

C1[O:3]C1.[CH3:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][C:13]1[CH:14]=[CH:15][C:16](O)=[CH:17][CH:18]=1>>[CH2:12]([C:13]1([OH:3])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18]1)[CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH3:4]

Participants

Reactant 2

HCID 17524-Nonylphenol3×

HCID 6354Ethylene Oxide5×

Product 1

HCID 12496141HCID 12496141, compound

Procedure

The same procedures as the first ethylene oxide addition step of Example 29 were carried out except that the amount of ethylene oxide was changed to 61 g (1.38 moles). That is, 0.69 mole of ethylene oxide was reacted with 1 mole of nonylphenol. Colorless liquid thus obtained was analyzed with liquid chromatography. The liquid contained 27.3% by weight of nonylphenol, 72.7% by weight of one molar ethylene oxide adduct, and trace amount of two molar ethylene oxide adduct of nonylphenol, respectively. The reaction product unfavorably formed a large amount of nonylcyclohexanol in the next hydrogenation step.

Workup

customColorless liquid thus obtained

Sources & evidence

ORD record: ord-7d54fec3161f4624a5f257c3e82e44cc
Source dataset: uspto-grants-2002_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06437194B2

Reaction notes

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