4-Chlorotoluene → Tris(4-methylphenyl)sulfanium Chloride

HRID 2305269Notes

Reaction equation

[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8]([C:10]2[CH:15]=[CH:14][C:13]([CH3:16])=[CH:12][CH:11]=2)=O)=[CH:4][CH:3]=1.[Cl:17][C:18]1[CH:23]=[CH:22][C:21]([CH3:24])=[CH:20][CH:19]=1>>[Cl-:17].[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S+:8]([C:18]2[CH:23]=[CH:22][C:21]([CH3:24])=[CH:20][CH:19]=2)[C:10]2[CH:15]=[CH:14][C:13]([CH3:16])=[CH:12][CH:11]=2)=[CH:4][CH:3]=1

Participants

Reactant 2

HCID 78104-Chlorotoluene

HCID 15680p-Tolyl sulfoxide

Product 1

HCID 5351245Tris(4-methylphenyl)sulfanium Chloride

Procedure

The end product was synthesized as in Synthesis Example 2 except that bis(4-methylphenyl)sulfoxide was used instead of the phenyl sulfoxide and 4-chlorotoluene was used instead of the chlorobenzene.

Sources & evidence

ORD record: ord-85e3bf56c29f49589486e7eb64d9dfe0
Source dataset: uspto-grants-2002_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06440634B1

Reaction notes

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