HRID2305271

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CC(C)(C)Oc1ccc([S+](c2ccccc2)c2ccccc2)cc1.[Cl-]

HCID23435201

(4-tert-Butoxyphenyl)(diphenyl)sulfanium chloride

C22H23ClOS

结构：O=S(=O)([O-])c1ccccc1OS(=O)(=O)c1ccccc1.[Na+]

HCID23711713

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)Oc1ccc([S+](c2ccccc2)c2ccccc2)cc1.O=S(=O)([O-])c1ccccc1OS(=O)(=O)c1ccccc1

HCID18432104

未命名化合物

PROCEDURE

实验过程

The end product was synthesized as in Synthesis Example 10 except that 4-tert-butoxyphenyldiphenylsulfonium chloride and sodium benzenesulfonyloxybenzenesulfonate were used.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-1e19fa9434d64f0e914d784500437a94
来源数据集: uspto-grants-2002_08
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06440634B1
来源说明: uspto-grants-2002_08

反应 SMILES

[Cl-].[C:2]([O:6][C:7]1[CH:12]=[CH:11][C:10]([S+:13]([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)=[CH:9][CH:8]=1)([CH3:5])([CH3:4])[CH3:3].[C:26]1([S:32]([O:35][C:36]2[CH:41]=[CH:40][CH:39]=[CH:38][C:37]=2[S:42]([O-:45])(=[O:44])=[O:43])(=[O:34])=[O:33])[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=1.[Na+]>>[C:26]1([S:32]([O:35][C:36]2[CH:41]=[CH:40][CH:39]=[CH:38][C:37]=2[S:42]([O-:45])(=[O:44])=[O:43])(=[O:34])=[O:33])[CH:27]=[CH:28][CH:29]=[CH:30][CH:31]=1.[C:2]([O:6][C:7]1[CH:12]=[CH:11][C:10]([S+:13]([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[C:14]2[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=2)=[CH:9][CH:8]=1)([CH3:5])([CH3:3])[CH3:4]