(4-tert-Butoxyphenyl)(diphenyl)sulfanium chloride → 4-Tert-butoxyphenyldiphenylsulfonium benzenesulfonyloxybenzenesulfonate
Reaction equation
[Cl-].[C:2]([O:6][C:7]1[CH:12]=[CH:11][C:10]([S+:13]([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)=[CH:9][CH:8]=1)([CH3:5])([CH3:4])[CH3:3].[C:26]1([S:32]([O:35][C:36]2[CH:41]=[CH:40][CH:39]=[CH:38][C:37]=2[S:42]([O-:45])(=[O:44])=[O:43])(=[O:34])=[O:33])[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=1.[Na+]>>[C:26]1([S:32]([O:35][C:36]2[CH:41]=[CH:40][CH:39]=[CH:38][C:37]=2[S:42]([O-:45])(=[O:44])=[O:43])(=[O:34])=[O:33])[CH:27]=[CH:28][CH:29]=[CH:30][CH:31]=1.[C:2]([O:6][C:7]1[CH:12]=[CH:11][C:10]([S+:13]([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[C:14]2[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=2)=[CH:9][CH:8]=1)([CH3:5])([CH3:3])[CH3:4]Participants
3
Procedure
The end product was synthesized as in Synthesis Example 10 except that 4-tert-butoxyphenyldiphenylsulfonium chloride and sodium benzenesulfonyloxybenzenesulfonate were used.
Sources & evidence
- ORD record
- ord-1e19fa9434d64f0e914d784500437a94
- Source dataset
- uspto-grants-2002_08
- Patent number
- US06440634B1
Reaction notes
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