反应详情

Into a flask were charged 250 g of the copolymer of 2-ethyl-2-adamantyl methacrylate and p-acetoxystyrene (20:80) obtained in Synthesis Example 4, 10.4 g (0.084 mol) of 4-dimethylaminopyridine and 202 g of methanol, and aged for 20 hours under reflux. After cooling, the reaction liquid was neutralized with 7.6 g (0.126 mol) of glacial acetic acid and poured into a large amount of water to precipitate a polymer. The deposited polymer was filtrated, dissolved in acetone, then, poured into a large amount of water to cause precipitation, and this operation was repeated three times in total for purification.

1. temperatureunder reflux
2. temperatureAfter cooling
3. customthe reaction liquid
4. customto precipitate a polymer
5. filtrationThe deposited polymer was filtrated
6. dissolutiondissolved in acetone
7. additionpoured into a large amount of water
8. customprecipitation
9. customtotal for purification