反应详情

Prepared from azide 30 by the same procedure as for amine 24 (Example 4). Amine hydrochloride 31 obtained as a colorless solid in 69% yield. 1H-NMR (CDCl3, TMS): 0.91 and 0.98 (total 12H, both s, c-Hex-3,5-CH3); 1.26 (2H, s, c-Hex-4-CH2); 1.68 (6H, s, —C(CH3)2N); 1.84 and 2.10 (both 2H, both s, c-Hex-2,6-CH2); 5.15 (1H, s, ═CH—) and 8.5 ppm (3H, br s, NH3+).