Benzyl Alcohol → HCID 68829627, compound

HRID 230741Notes

Reaction equation

HRID 230741 reaction equation
[C:1]123C(=O)[O:10][C:8](=[O:9])[CH:2]1[CH2:3][CH:4]([CH2:7]2)[CH2:5][CH2:6]3.[CH2:13]([OH:20])[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>C(Cl)(Cl)Cl>[CH2:13]([O:20][CH:3]1[CH:4]2[CH2:7][CH:1]([CH2:6][CH2:5]2)[CH:2]1[C:8]([OH:10])=[O:9])[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1

Participants

4

Reactant 2

HCID 244Benzyl AlcoholHCID 20223186HCID 20223186, compound

Product 1

HCID 68829627HCID 68829627, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

33.2 g (0.2 mol) bicyclo[2.2.1]heptane dicarboxylic anhydride and 27 g (0.25 mol) benzyl alcohol were charged to 500 ml chloroform in a 1 L round bottom flask. The system was refluxed for 16 hours with magnetic stirring. The solvent was then removed by rotary evaporator. The solid was then dried and grounded. The product was characterized using FTIR and GC-MS. The yield was quantitative.

Workup

  1. temperatureThe system was refluxed for 16 hours with magnetic stirring
  2. customThe solvent was then removed by rotary evaporator
  3. customThe solid was then dried

Sources & evidence

ORD record
ord-cac69a0dfc824d5ab006b65f1521438d
Source dataset
uspto-grants-2009_07
Patent number
US07566797B2

Reaction notes

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