HRID2307545

反应详情

EQUATION

反应方程式

REACTANTS

反应物

反应SMILES：O=C(OCc1ccc(CBr)cc1COC(=O)c1ccccc1)c1ccccc1

HCID22345618

未命名化合物

HCID22606886

未命名化合物

反应SMILES：O=C(OCC1=CC=C(c2ccccc2)C(OCc2ccccc2)C1(COC(=O)c1ccccc1)C(=O)[O-])c1ccccc1

HCID131724686

未命名化合物

PRODUCTS

产物

反应SMILES：CCOC(=O)c1cccc(-c2cccc(OCc3ccc(COC(=O)c4ccccc4)c(COC(=O)c4ccccc4)c3)c2)c1

HCID22606919

未命名化合物

PROCEDURE

实验过程

In a manner similar to that of Example 1(i), by reaction of 1 g (4.1 mmol) of ethyl 3′-hydroxybiphenyl-3-carboxylate with 1.98 g (4.5 mmol) of 3,4-bis(benzoyloxymethyl)benzyl bromide, 2.1 g (85%) of ethyl 3′-[3,4-bis(benzoyloxymethyl)benzyloxylbiphenyl-3-carboxylate are obtained.

WORKUP

后处理

customare obtained

来源与证据

来源类型: Open Reaction Database
ORD记录: ord-5abb36a3eb864159880f263ffa46a65b
来源数据集: uspto-grants-2004_12
DOI: 10.6084/m9.figshare.5104873.v1
专利号: US06831106B1
来源说明: uspto-grants-2004_12

反应SMILES

[OH:1][C:2]1[CH:3]=[C:4]([C:8]2[CH:13]=[CH:12][CH:11]=[C:10]([C:14]([O:16][CH2:17][CH3:18])=[O:15])[CH:9]=2)[CH:5]=[CH:6][CH:7]=1.[C:19]([O:27][CH2:28][C:29]1[CH:30]=[C:31]([CH:34]=[CH:35][C:36]=1[CH2:37][O:38][C:39](=[O:46])[C:40]1[CH:45]=[CH:44][CH:43]=[CH:42][CH:41]=1)[CH2:32]Br)(=[O:26])[C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1.C(OCC1(C([O-])=O)C(COC(=O)C2C=CC=CC=2)=CC=C(C2C=CC=CC=2)C1OCC1C=CC=CC=1)(=O)C1C=CC=CC=1>>[C:19]([O:27][CH2:28][C:29]1[CH:30]=[C:31]([CH:34]=[CH:35][C:36]=1[CH2:37][O:38][C:39](=[O:46])[C:40]1[CH:41]=[CH:42][CH:43]=[CH:44][CH:45]=1)[CH2:32][O:1][C:2]1[CH:3]=[C:4]([C:8]2[CH:13]=[CH:12][CH:11]=[C:10]([C:14]([O:16][CH2:17][CH3:18])=[O:15])[CH:9]=2)[CH:5]=[CH:6][CH:7]=1)(=[O:26])[C:20]1[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=1