3,4-Bis(benzoyloxymethyl)benzyl bromide → HCID 131724688, compound

HRID 2307547Notes

Reaction equation

HRID 2307547 reaction equation
O[C:2]1[CH:3]=[C:4]([C:8]2[CH:13]=[CH:12][CH:11]=[C:10]([CH2:14][C:15]([O:17][CH3:18])=[O:16])[CH:9]=2)[CH:5]=[CH:6][CH:7]=1.C(OCC1C=C(C=CC=1COC(=O)C1C=CC=CC=1)CBr)(=O)C1C=CC=CC=1.[C:47]([O:55][CH2:56][C:57]1[CH:58]=[C:59]([CH:79]=[CH:80][C:81]=1[CH2:82][O:83][C:84](=[O:91])[C:85]1[CH:90]=[CH:89][CH:88]=[CH:87][CH:86]=1)[CH2:60][O:61]C1C=C(C2C=CC=C(CC(OC)=O)C=2)C=CC=1)(=[O:54])[C:48]1[CH:53]=[CH:52][CH:51]=[CH:50][CH:49]=1>>[C:47]([O:55][CH2:56][C:57]1[CH:58]=[C:59]([CH:79]=[CH:80][C:81]=1[CH2:82][O:83][C:84](=[O:91])[C:85]1[CH:86]=[CH:87][CH:88]=[CH:89][CH:90]=1)[CH2:60][O:61][C:10]1([CH2:14][C:15]([O:17][CH3:18])=[O:16])[CH:11]=[CH:12][CH:13]=[C:8]([C:4]2[CH:5]=[CH:6][CH:7]=[CH:2][CH:3]=2)[CH2:9]1)(=[O:54])[C:48]1[CH:49]=[CH:50][CH:51]=[CH:52][CH:53]=1

Participants

4

Reactant 3

HCID 223456183,4-Bis(benzoyloxymethyl)benzyl bromideHCID 57728616HCID 57728616, compoundHCID 90885832HCID 90885832, compound

Product 1

HCID 131724688HCID 131724688, compound

Procedure

In a manner similar to that of Example 1(i), by reaction of 1 g (4.1 mmol) of methyl (3′-hydroxybiphenyl-3-yl)acetate with 2 g (4.5 mmol) of 3,4-bis(benzoyloxymethyl)benzyl bromide, 2.2 g (91%) of methyl {3′-[3,4-bis(benzoyloxymethyl)benzyloxy]-biphenyl-3-yl}acetate are obtained.

Workup

  1. customare obtained

Sources & evidence

ORD record
ord-22ca75ceb8534e7a85b48ed7198cc9e7
Source dataset
uspto-grants-2004_12
Patent number
US06831106B1

Reaction notes

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