HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Carbonate → Methyl 3'-[3,4-bis(1-phenylmethanoyloxymethyl)benzyloxy]-2,2'-dimethylbiphenyl-4-carboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 3,4-Bis(benzoyloxymethyl)benzyl bromide | HCID 22345618 | — |
| Reactant | Methyl 3'-hydroxy-2,2'-dimethylbiphenyl-4-carboxylate | HCID 22606889 | — |
| Product | Methyl 3'-[3,4-bis(1-phenylmethanoyloxymethyl)benzyloxy]-2,2'-dimethylbiphenyl-4-carboxylate | HCID 22606870 | — |
Reaction Steps
In a manner similar to that of Example 1(i), by reaction of 515 mg (2 mmol) of methyl 3′-hydroxy-2,2′-dimethylbiphenyl-4-carboxylate with 880 mg (2 mmol) of 3,4-bis(benzoyloxymethyl)benzyl bromide and 300 mg (2.2 mmol) of potassium carbonate, the desired product is obtained in the form of a colourless oil (m=1.22 g; Y=99%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06831106B1 |
| Source dataset | uspto-grants-2004_12 |
| ORD ID | ord-671fe4123c53468cb1bac241042bcb7b |
| Source note | uspto-grants-2004_12 |