Benzenamine, 3-bromo-4-methyl- → 3-Bromo-4-methylphenol

HRID 2307563Notes

Reaction equation

HRID 2307563 reaction equation
[Br:1][C:2]1[CH:3]=[C:4](N)[CH:5]=[CH:6][C:7]=1[CH3:8].N([O-])=[O:11].[Na+]>>[Br:1][C:2]1[CH:3]=[C:4]([OH:11])[CH:5]=[CH:6][C:7]=1[CH3:8]

Participants

3

Reactant 2

HCID 82187Benzenamine, 3-bromo-4-methyl-HCID 23668193Sodium Nitrite

Product 1

HCID 103079133-Bromo-4-methylphenol

Procedure

In a manner similar to that of Example 11(a), by reaction of 20 g (107 mmol) of 3-bromo-4-methylphenylamine with 8.9 g (129 mmol) of sodium nitrite, a brown oil is obtained, without purification (m=20 g; Y=100%).

Workup

  1. customa brown oil is obtained, without purification (m=20 g; Y=100%)

Sources & evidence

ORD record
ord-fdee88cbde844f6caddca99abb5e9b5c
Source dataset
uspto-grants-2004_12
Patent number
US06831106B1

Reaction notes

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