HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Carbonate → Methyl 5'-[3,4-bis(1-phenylmethanoyloxymethyl)-benzyloxy]-2,2'-dimethylbiphenyl-4-carboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 3,4-Bis(benzoyloxymethyl)benzyl bromide | HCID 22345618 | — |
| Reactant | Methyl 5'-hydroxy-2,2'-dimethylbiphenyl-4-carboxylate | HCID 22606936 | — |
| Product | Methyl 5'-[3,4-bis(1-phenylmethanoyloxymethyl)-benzyloxy]-2,2'-dimethylbiphenyl-4-carboxylate | HCID 22606884 | — |
Reaction Steps
In a manner similar to that of Example 1(i), by reaction of 2.24 g (8.7 mmol) of methyl 5′-hydroxy-2,2′-dimethylbiphenyl-4-carboxylate with 4.20 mg (9.6 mmol) of 3,4-bis(benzoyloxymethyl)benzyl bromide and 1.26 g (9 mmol) of potassium carbonate, the desired product is obtained in the form of a colourless oil (m=5.34 g; Y=99%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06831106B1 |
| Source dataset | uspto-grants-2004_12 |
| ORD ID | ord-1a401cad74374004bf05d3b515ce2317 |
| Source note | uspto-grants-2004_12 |