HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Carbonate → Methyl 3'-(3,4-bis(1-phenylmethanoyloxymethyl)-benzyloxy]-2,6-dimethylbiphenyl-4-carboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 3,4-Bis(benzoyloxymethyl)benzyl bromide | HCID 22345618 | — |
| Reactant | Methyl 3'-hydroxy-2,6-dimethylbiphenyl-4-carboxylate | HCID 22606868 | — |
| Product | Methyl 3'-(3,4-bis(1-phenylmethanoyloxymethyl)-benzyloxy]-2,6-dimethylbiphenyl-4-carboxylate | HCID 22606946 | — |
Reaction Steps
In a manner similar to that of Example 1(i), by reaction of 4.49 g (17.5 mmol) of methyl 3′-hydroxy-2,6-dimethylbiphenyl-4-carboxylate with 8.46 g (19 mmol) of 3,4-bis(benzoyloxymethyl)benzyl bromide and 2.54 g (18 mmol) of potassium carbonate, the desired product is obtained in the form of a yellow oil (m=7.4 g; Y=69%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06831106B1 |
| Source dataset | uspto-grants-2004_12 |
| ORD ID | ord-54586624f33b45df9c957176a61d95b0 |
| Source note | uspto-grants-2004_12 |