HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → HCID 53645761, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | 1-[3-(Acetylthio)-2-(methoxycarbonylmethyl)propanoyl]-L-proline | HCID 54112383 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Solvent | Methanol | HCID 887 | — |
| Solvent | Sodium Hydroxide | HCID 14798 | — |
| Product | HCID 53645761 | HCID 53645761 | — |
Reaction Steps
To a solution of the product from Example 81 (3.0 g.) in methanol (60 ml.), 1N sodium hydroxide (60 ml.) is added. After 4 hours, the solution is applied to a column of Dowex 50 ion exchange resin in the hydrogen cycle, and the desired material is eluted with water to yield 2.3 g. of the named product Rf : 0.2 (silica gel-benzene:acetic acid, 75:25).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04690936 |
| Source dataset | uspto-grants-1987_09 |
| ORD ID | ord-08991bdd368c4e7f9da1d9273d952816 |
| Source note | uspto-grants-1987_09 |