Diethyl Ether → HCID 20187649, compound

Participants

Reaction Conditions

Reaction Steps

There was added 2.6 moles of butyl lithium in hexane over a 15 minute period to a mixture of 50 grams of the 3-bromo-N,N-bis(trimethylsilyl)aniline in 400 ml. of anhydrous ether cooled to 0° C. under a nitrogen atmosphere. The resulting reaction mixture was allowed to stir for an additional 2 hours at 0° C. The mixture was then added to a mixture of 100 ml. of anhydrous ether and 16.06 grams of 1,3-dichloro-1,1,3,3-tetramethyldisiloxane at 0° C. After the solution was filtered and the solvents were removed under reduced pressure, there was obtained a 77% yield of 1,3-bis[N,N-bis(trimethylsilyl)-3-aminophenyl]-1,1,3,3-tetramethyldisiloxane in the form of a pale-yellow oil having a boiling point of about 169°-174° C.

Provenance & Evidence