関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Ethylene carbonate | HCID 7303 | — |
| 反応物 | p-Isopropenylphenol | HCID 584247 | — |
| 反応物 | Potassium fluoride dihydrate | HCID 23708904 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | 2-(4-(1-Methylethenyl)phenoxy)ethanol | HCID 13750613 | 69% |
反応手順
A mixture of 20 g p-isopropenylphenol, 1.1 equivalents ethylene carbonate, 0.02 equivalent potassium fluoride dihydrate, and 200 ml N,N-dimethylformamide (DMF) was heated at about 150° C. for about 1.5 hours. After removal of DMF under reduced pressure, the crude product was distilled. 2-(4-(1-Methylethenyl)phenoxy)ethanol, bp 143° C./7 torr, was obtained as a white solid in 69% yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04691042 |
|---|
| 出典データセット | uspto-grants-1987_09 |
|---|
| ORD ID | ord-ab2fa38553ff41ddaac4e08279e66ef0 |
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| 出典メモ | uspto-grants-1987_09 |
|---|
