HRID2309175

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID192414

未命名化合物

结构：CC(C)[C@H](NC(=O)CNC(=O)[C@H](Cc1ccccc1)NC(=O)CNC(=O)OC(C)(C)C)C(=O)NCC(=O)OCc1ccccc1

HCID131715248

未命名化合物

PRODUCTS

生成物

结构：CC(C)[C@H](NC(=O)CNC(=O)[C@H](Cc1ccccc1)NC(=O)CNC(=O)OC(C)(C)C)C(=O)NCC(=O)O

HCID131715252

未命名化合物

PROCEDURE

实验过程

IV was hydrogenated and worked up as described for VIII to obtain the product in quantitative yield. Rf3 0.16. Anal. calcd. for C25H37N5O8 ·H2O: C 54.23, H 7.10, N 12.65%. Found: C 54.14, H 6.93, N 12.21%.

WORKUP

后处理

customto obtain the product in quantitative yield

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-c912b1063af843a9bccf09bfc0009c04
来源数据集: uspto-grants-1987_09
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04693718
来源说明: uspto-grants-1987_09

反应 SMILES

[NH:1]([C:39]([O:41][C:42]([CH3:45])([CH3:44])[CH3:43])=[O:40])[CH2:2][C:3]([NH:5][C@H:6]([C:14]([NH:16][CH2:17][C:18]([NH:20][C@H:21]([C:25]([NH:27][CH2:28][C:29]([O:31]CC1C=CC=CC=1)=[O:30])=[O:26])[CH:22]([CH3:24])[CH3:23])=[O:19])=[O:15])[CH2:7][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)=[O:4].N(C(OC(C)(C)C)=O)[C@H](C(NCC(O)=O)=O)C>>[NH:1]([C:39]([O:41][C:42]([CH3:44])([CH3:43])[CH3:45])=[O:40])[CH2:2][C:3]([NH:5][C@H:6]([C:14]([NH:16][CH2:17][C:18]([NH:20][C@H:21]([C:25]([NH:27][CH2:28][C:29]([OH:31])=[O:30])=[O:26])[CH:22]([CH3:24])[CH3:23])=[O:19])=[O:15])[CH2:7][C:8]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1)=[O:4]