Acetyl chloride → HCID 15499742, compound

HRID 2309572Notes

Reaction equation

HRID 2309572 reaction equation
C[O:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[CH2:9][C:10]([O:12][CH3:13])=[O:11].[C:14](Cl)(=[O:16])[CH3:15].[Cl-].[Al+3].[Cl-].[Cl-]>C(Cl)Cl>[C:14]([C:6]1[CH:7]=[CH:8][C:3]([OH:2])=[C:4]([CH2:9][C:10]([O:12][CH3:13])=[O:11])[CH:5]=1)(=[O:16])[CH3:15]

Participants

5

Reactant 3

HCID 6367Acetyl chlorideHCID 99590Methyl 2-methoxybenzeneacetateHCID 6451240Aluminum(III) Chloride

Product 1

HCID 15499742HCID 15499742, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent2×

Procedure

36 g of methyl 2-methoxy-benzeneacetate and 15.7 g of acetyl chloride are dissolved in 100 ml of methylene chloride, the resultant solution then being added dropwise to a suspension of 100 g of aluminum chloride in 300 ml methylene chloride. The solution is boiled for 5 hours, poured onto ice water and filtered. The crystals are washed with water and methylene chloride.

Workup

  1. additionpoured onto ice water
  2. filtrationfiltered
  3. washThe crystals are washed with water and methylene chloride

Sources & evidence

ORD record
ord-aa69e46fe2f6439590cfe175b9c2c8db
Source dataset
uspto-grants-1987_09
Patent number
US04695648

Reaction notes

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