Sodium Hydroxide → HCID 20184733, compound

HRID 2309748Notes

Reaction equation

HRID 2309748 reaction equation
C[O:2][C:3]([CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH:10]([CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH3:33])[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][C:16]([O:18]C)=[O:17])=[O:4].[OH-].[Na+]>C(O)C>[CH2:20]([CH:10]([CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][C:16]([OH:18])=[O:17])[CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][C:3]([OH:4])=[O:2])[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH3:33]

Participants

4

Reactant 2

HCID 14798Sodium HydroxideHCID 54382064HCID 54382064, compound

Product 1

HCID 20184733HCID 20184733, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A solution of the diester (0.2 g; from example 75) in ethanol (5 ml) was treated with 10% aqueous NaOH (2.5 ml) exactly as in example 5 to provide a crystalline solid, m.p. 48°-50° C.

Workup

  1. customto provide a crystalline solid, m.p. 48°-50° C.

Sources & evidence

ORD record
ord-0c9c9d8d78154ac4963cb69835afd0a6
Source dataset
uspto-grants-1987_09
Patent number
US04696946

Reaction notes

Loading…