化工社化工社 化学情報印刷レポート · 研究参考用
Samarium → Anthracene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Samarium | HCID 23951 | — |
| 反応物 | Anthracene ytterbium | HCID 20034756 | — |
| 溶媒 | 1,2-Dimethoxyethane | HCID 8071 | — |
| 生成物 | Anthracene | HCID 8418 | — |
反応手順
Example 1 is repeated, but with the use of 20 m.g atoms of samarium powder instead of ytterbium. Anthracene samarium (1/1) solvated with DME, is obtained as a purple compound with a substantially quantitative yield with respect to anthracene. The complex, treated with a water excess, gives dihydroanthracene with a quantitative yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04845201 |
| 出典データセット | uspto-grants-1989_07 |
| ORD ID | ord-5448869b772e453abe847c556d786061 |
| 出典メモ | uspto-grants-1989_07 |