HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → 9,10-Dihydroanthracene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | Anthracene | HCID 8418 | — |
| Reactant | Cerium | HCID 23974 | — |
| Solvent | 1,2-Dimethoxyethane | HCID 8071 | — |
| Product | 9,10-Dihydroanthracene | HCID 11940 | 59% |
Reaction Steps
1.14 mmole of anthracene is reacted with 4.57 m atoms of cerium as powder in 7.5 ml of DME in the conditions of example 9 with application of ultrasound, thus producing anthracenecerium. After action of a methanol excess and the usual treatment, 9,10-dihydroanthracene was isolated with a yield of 59%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04845201 |
| Source dataset | uspto-grants-1989_07 |
| ORD ID | ord-4d94dcbf8d314500877ef0fa80aacbef |
| Source note | uspto-grants-1989_07 |