Trimethylamine → HCID 14498226, compound

HRID 231259Notes

Reaction equation

HRID 231259 reaction equation
[CH3:1][O:2][CH:3]([CH2:16][O:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH3:35])[CH2:4][S:5]([CH2:8][CH2:9][CH2:10][O:11][S:12]([CH3:15])(=[O:14])=[O:13])(=[O:7])=[O:6].[CH3:36][N:37]([CH3:39])[CH3:38]>C1(C)C=CC=CC=1>[S:12]([O-:14])(=[O:13])(=[O:11])[CH3:15].[CH3:1][O:2][CH:3]([CH2:16][O:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH3:35])[CH2:4][S:5]([CH2:8][CH2:9][CH2:10][N+:37]([CH3:39])([CH3:38])[CH3:36])(=[O:7])=[O:6]

Participants

4

Reactant 2

HCID 1146TrimethylamineHCID 20034823HCID 20034823, compound

Product 1

HCID 14498226HCID 14498226, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

In 10 ml of toluene containing 2.0 g of trimethylamine are dissolved 1.45 g of 3-mesyloxypropyl 2-methoxy-3-octadecyloxypropyl sulfone and the solution is stirred at room temperature for 3 days. The reaction solution is then concentrated to dryness and the residue is purified by silica gel column chromatography to give 1.04 g of the captioned compound.

Workup

  1. concentrationThe reaction solution is then concentrated to dryness
  2. customthe residue is purified by silica gel column chromatography

Sources & evidence

ORD record
ord-3b48296095f74806a6d137071f19c71e
Source dataset
uspto-grants-1989_07
Patent number
US04845219

Reaction notes

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