反应详情

温度

70 °C

50 g (0.073 mol) of sodium heptadecafluorododecyl 2-hydroxy-3-chloropropyl phosphate was charged into a reactor, to which 1000 ml of ethanol was added, followed by agitation and heating to 70° C. to obtain a uniform mixture. Thereafter, the reaction system was cooled down to 30° C., to which was gradually added 40.5 g (0.073 mol) of a 0.0018 mol/g sodium hydroxide ethanol solution, followed by agitation for 4 hours while keeping the temperature. The HPLC analysis revealed the disappearance of a peak of the starting material with a peak for the resultant new product appearing. The resultant NaCl precipitate was removed by filtration and the ethanol was distilled off under reduced pressure to obtain 47 g (yield: 99%) of sodium heptadecafluorododecyl glycidyl phosphate.

1. additionwas added
2. customto obtain a uniform mixture
3. temperatureThereafter, the reaction system was cooled down to 30° C., to which
4. customThe resultant NaCl precipitate was removed by filtration
5. distillationthe ethanol was distilled off under reduced pressure