Nitric Acid → HCID 70379606, compound

HRID 231371Notes

Reaction equation

HRID 231371 reaction equation
[F:1][CH:2]([O:7][C:8]1[CH:13]=[CH:12][C:11]([N:14]2[CH2:18][CH2:17][O:16][C:15]2=[O:19])=[CH:10][CH:9]=1)[C:3]([F:6])([F:5])[F:4].[N+:20]([O-])([OH:22])=[O:21]>S(=O)(=O)(O)O>[N+:20]([C:12]1[CH:13]=[C:8]([O:7][CH:2]([F:1])[C:3]([F:5])([F:4])[F:6])[CH:9]=[CH:10][C:11]=1[N:14]1[CH2:18][CH2:17][O:16][C:15]1=[O:19])([O-:22])=[O:21]

Participants

4

Reactant 2

HCID 944Nitric AcidHCID 70379468HCID 70379468, compound

Product 1

HCID 70379606HCID 70379606, compound

Reagents, catalysts & solvents 1

HCID 1118Sulfuric AcidSolvent2×

Procedure

2.79 g (10 mmoles) of the oxazolidinon of Step 2 are dissolved in 7 ml concentrated sulfuric acid and nitrated at 0° C. with a mixture of 0.43 ml (10 mmoles) fuming nitric acid and 3.6 ml concentrated sulfuric acid.

Sources & evidence

ORD record
ord-72f79cdae65c44ccb44f9b771dbd7ecc
Source dataset
uspto-grants-1989_07
Patent number
US04845294

Reaction notes

Loading…