Nitrobenzene → 4-Nitrophenylphenyl Sulfide

HRID 231743Notes

Reaction equation

HRID 231743 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=2[S:16]([C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][C:20]=2[C:25]2[CH:30]=[CH:29][C:28]([N+:31]([O-:33])=[O:32])=[CH:27][CH:26]=2)(=O)=O)=[CH:6][CH:5]=1)([O-:3])=[O:2].[N+](C1C=CC=CC=1)([O-])=O.C1([S-])C=CC=CC=1.[Na+]>O>[N+:31]([C:28]1[CH:27]=[CH:26][C:25]([C:20]2[CH:21]=[CH:22][CH:23]=[CH:24][C:19]=2[S:16][C:11]2[CH:12]=[CH:13][CH:14]=[CH:15][C:10]=2[C:7]2[CH:6]=[CH:5][C:4]([N+:1]([O-:3])=[O:2])=[CH:9][CH:8]=2)=[CH:30][CH:29]=1)([O-:33])=[O:32]

Participants

5

Reactant 3

HCID 7416NitrobenzeneHCID 4110039Sodium benzenethiolateHCID 542897844-Nitrophenylphenyl sulfone

Product 1

HCID 545005924-Nitrophenylphenyl Sulfide

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

An amount of 21.4 g (0.08 mole) of the thus obtained 4-nitrophenylphenyl sulfone was dissolved in a two phase solvent composed of a mixture of 80 g of nitrobenzene and 80 g of water, and was reacted with sodium thiophenolate in the same manner as in Example 1.

Sources & evidence

ORD record
ord-6935791bf87f43eca19ae100afb76aea
Source dataset
uspto-grants-1989_07
Patent number
US04849138

Reaction notes

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