HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tetrahydrofuran → HCID 10942917, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tetrahydrofuran | HCID 8028 | — |
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | 4-Phenylcyclohexanone | HCID 78605 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 10942917 | HCID 10942917 | 10% |
Reaction Steps
BDAM (2.83 grams) was suspended in 40 milliliters of toluene and 2.2 milliliters of THF were added dropwise. After 10 minutes of stirring, 2.10 grams of 4-phenylcyclohexanone were added. The reaction mixture was refluxed for 1 hour and hydrolyzed with hydrated Ca(OH)2 in the presence of Et3N. After the usual work up, 0.21 grams of 4-phenyl-1-methylenecyclohexane was isolated (10% yield).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04849574 |
| Source dataset | uspto-grants-1989_07 |
| ORD ID | ord-bac90a4f387942999a8e79c5be428819 |
| Source note | uspto-grants-1989_07 |