Thiophosgene → HCID 57220997, compound

Participants

Reaction Steps

S-(Pentafluorophenyl) 4-(hydroxy)thiobenzoate (6.82 g) in dry chloroform (120 ml) was treated with thiophosgene (2.4 ml). This solution was treated with sodium hydroxide (0.85 g) in water (3 ml) with vigorous stirring for 10 minutes. Stirring was continued for 2 hours, when the solution was treated with calcium chloride and stirred for a further hour. Filtration and evaporation of the filtrate gave the title compound (7.6 g) as a homogeneous oil.

Provenance & Evidence