HuagongsheHuagongshe Chemistry Print Report · For research reference only
Thiophosgene → HCID 57187971, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Thiophosgene | HCID 10040 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | Calcium Chloride | HCID 5284359 | — |
| Reactant | Benzenecarbothioic acid, 4-hydroxy-, S-(4-cyanophenyl) ester | HCID 11357276 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | HCID 57187971 | HCID 57187971 | — |
Reaction Steps
A solution of 566 mg of sodium hydroxide in 5 ml of water was added dropwise with vigorous stirring to a solution of 3.00 g of S-(4-cyanophenyl) 4-(hydroxy)thiobenzoate and 1.35 ml of thiophosgene in 60 ml of chloroform. Stirring was continued for 2 hours when the filtered solution was treated with calcium chloride and stirred for a further 30 minutes. Evaporation of the filtered solution gave 3.66 g of the title compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04849419 |
| Source dataset | uspto-grants-1989_07 |
| ORD ID | ord-cf2ce84f117c446aa002c3ec293137be |
| Source note | uspto-grants-1989_07 |