Thionyl Chloride → HCID 14149870, compound

HRID 231994Notes

Reaction equation

HRID 231994 reaction equation
[Br:1][C:2]1[C:3]([Cl:13])=[C:4]([CH:8]=[C:9]([F:12])[C:10]=1[Cl:11])[C:5](O)=[O:6].S(Cl)([Cl:16])=O>>[Br:1][C:2]1[C:3]([Cl:13])=[C:4]([CH:8]=[C:9]([F:12])[C:10]=1[Cl:11])[C:5]([Cl:16])=[O:6]

Participants

3

Reactant 2

HCID 24386Thionyl ChlorideHCID 9838877HCID 9838877, compound

Product 1

HCID 14149870HCID 14149870, compound

Procedure

58.3 g (0.2 mol) of 3-bromo-2,4-dichloro-5-fluorobenzoic acid are refluxed for 4 hours in 350 ml of thionyl chloride until the gas evolution ceases. Excess thionyl chloride is removed by distillation, and the residue is fractionated.

Workup

  1. customExcess thionyl chloride is removed by distillation

Sources & evidence

ORD record
ord-bdcf6a0dc61d4d68a60c51d7279a91ba
Source dataset
uspto-grants-1989_07
Patent number
US04851160

Reaction notes

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