2-bromocyclododecanone → HCID 20031504, compound

HRID 232339Notes

Reaction equation

[CH2:1]1[CH2:13][CH2:12][CH2:11][CH2:10][CH:9](Br)[C:7](=[O:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[C:15]([OH:21])(=[O:20])[CH2:16][C:17]([OH:19])=[O:18].[Na]>>[O:8]=[C:7]1[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH2:1][CH2:13][CH2:12][CH2:11][CH2:10][CH:9]1[CH:16]([C:15]([OH:21])=[O:20])[C:17]([OH:19])=[O:18]

Participants

Reactant 2

HCID 357602-bromocyclododecanone

HCID 53445323141-95-7

Product 1

HCID 20031504HCID 20031504, compound

Procedure

Reaction of α-bromocyclododecanone VI with the dialkyl ester of sodium malonic acid to obtain the dialkyl ester of 2-(2-oxocyclododec-1-yl)malonic acid VII.

Sources & evidence

ORD record: ord-79a9619942ca40ed9e2d6804fcb10bcf
Source dataset: uspto-grants-1989_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04851552

Reaction notes

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