Methoxide → 1,13-dimethyl-10-(triphenylsilyloxymethyl)-2,6,7,8,9,11,12,14,15,16-decahydro-1H-cyclopenta[a]phenanthrene-3,17-dione
Reaction equation
[CH3:65][O-:66].[OH:1][CH2:2][C:3]12[CH:4]3[CH:5]([CH:6]4[C:7]([CH3:10])([CH2:8][CH2:9]3)[C:11](=[O:12])[CH2:13][CH2:14]4)[CH2:15][CH:16]([CH3:17])[C:18]1=[CH:19][C:20](=[O:21])[CH2:22][CH2:23]2.[c:24]1([Si:30]([O:31][CH2:32][C:33]23[CH2:34][CH2:35][C:36](=[O:52])[CH:37]=[C:38]2[CH2:39][CH2:40][CH:41]2[CH:42]4[CH2:43][CH2:44][C:45](=[O:51])[C:46]4([CH3:47])[CH2:48][CH2:49][CH:50]32)([c:53]2[cH:54][cH:55][cH:56][cH:57][cH:58]2)[c:59]2[cH:60][cH:61][cH:62][cH:63][cH:64]2)[cH:25][cH:26][cH:27][cH:28][cH:29]1>>[CH3:2][CH:34]1[C:33]2([CH2:32][O:31][Si:30]([c:24]3[cH:25][cH:26][cH:27][cH:28][cH:29]3)([c:53]3[cH:54][cH:55][cH:56][cH:57][cH:58]3)[c:59]3[cH:60][cH:61][cH:62][cH:63][cH:64]3)[C:38](=[CH:37][C:36](=[O:52])[CH2:35]1)[CH2:39][CH2:40][CH:41]1[CH:42]3[CH2:43][CH2:44][C:45](=[O:51])[C:46]3([CH3:47])[CH2:48][CH2:49][CH:50]21Participants
4
Reactant 3
Product 1
Sources & evidence
- ORD record
- ord-d5a88b3d13244a539c23c460f8fe3d6e
- Source dataset
- Training data from https://doi.org/10.1039/C8SC04228D (10/10)
Reaction notes
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