Toluene → benzyl N-(1-methyl-5-phenyl-2-sulfanylidene-3H-1,4-benzodiazepin-3-yl)carbamate

HRID 2327109Notes

Reaction equation

HRID 2327109 reaction equation
[CH3:1][N:2]1[C:3](=[O:30])[CH:4]([NH:19][C:20]([O:21][CH2:22][c:23]2[cH:24][cH:25][cH:26][cH:27][cH:28]2)=[O:29])[N:5]=[C:6]([c:13]2[cH:14][cH:15][cH:16][cH:17][cH:18]2)[c:7]2[c:8]1[cH:9][cH:10][cH:11][cH:12]2.[CH3:31][O:32][c:33]1[cH:34][cH:35][c:36]([P:37]2(=[S:38])[S:39][P:41](=[S:42])([c:43]3[cH:44][cH:45][c:46]([O:47][CH3:48])[cH:49][cH:50]3)[S:40]2)[cH:51][cH:52]1.[CH3:53][c:54]1[cH:55][cH:56][cH:57][cH:58][cH:59]1>>[CH3:1][N:2]1[C:3](=[S:40])[CH:4]([NH:19][C:20]([O:21][CH2:22][c:23]2[cH:24][cH:25][cH:26][cH:27][cH:28]2)=[O:29])[N:5]=[C:6]([c:13]2[cH:14][cH:15][cH:16][cH:17][cH:18]2)[c:7]2[c:8]1[cH:9][cH:10][cH:11][cH:12]2

Participants

4

Reactant 3

HCID 1140TolueneHCID 87949Lawesson's reagentHCID 18969006benzyl 1-methyl-2-oxo-5-phenyl-2,3-dihydro-1H-benzo[e][1,4]diazepin-3-ylcarbamate

Product 1

HCID 18968934benzyl N-(1-methyl-5-phenyl-2-sulfanylidene-3H-1,4-benzodiazepin-3-yl)carbamate

Sources & evidence

ORD record
ord-e1c42f858c0142d2b9dde3a6ed3f2b3e
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

Loading…